Could you hide from a FLIR camera with this?
Should be able to. What you won't be able to hide from with this is sensor-fusion night vision that merges thermal and night vision images into one image.
Is that like military/satellite level or do the cops have that?
It's just a brand. Hunters can buy them.
I think you'd still be fine because night vision is just light amplification. Amplifying the light with infravision isn't going to see through material that blocks infrared light.
The space blanket doesn't block infrared, though, it just blocks heat. So the environment light (moonlight/stars, IR laser etc) would still reflect off of the blanket.
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