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[–] 3 pts

Citric acid works better than CLR. You can buy the powder online or in a home brew shop.

Mixing baking soda and vinegar is pointless as they're counteracting each other.

[–] 0 pt

The physical action caused by vinegar and baking soda bubbling furiously breaks up stuff.

[–] 0 pt

Not unless there's a way for it to build up pressure. If the hard water deposits would even allow pressure to build it would mean there was no way for the vinegar and baking soda to penetrate.